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A, C3H7COOH + C2H5OH → C3H2CÔC2H5 + H2O

B, 1,88

27 tháng 4
a. Viết phương trình phản ứng Phản ứng giữa butyric acid ( 𝐶𝐻3 [ 𝐶𝐻2 ]2𝐶𝑂𝑂𝐻) và ethanol ( C2H5OH𝐶2𝐻5𝑂𝐻) có sự xúc tác của  H2SO4𝐻2𝑆𝑂4 đặc và đun nóng:
CH3[CH2]2COOH+C2H5OHCH3[CH2]2COOC2H5+H2O𝐶𝐻3[𝐶𝐻2]2𝐶𝑂𝑂𝐻+𝐶2𝐻5𝑂𝐻𝐻2𝑆𝑂4đc,𝑡∘𝐶𝐻3[𝐶𝐻2]2𝐶𝑂𝑂𝐶2𝐻5+𝐻2𝑂(Sản phẩm thu được là ethyl butyrate)
b. Tính giá trị của  m𝑚 Để tính khối lượng ester, chúng ta thực hiện các bước sau: 1. Tính số mol các chất tham gia:
  • Phân tử khối butyric acid ( C4H8O2𝐶4𝐻8𝑂2):  𝑀 =88 g/mol
    ⇒𝑛butyricacid =1,7688 =0 , 02 mol
  • Phân tử khối ethanol ( C2H6O𝐶2𝐻6𝑂):  𝑀 =46 g/mol
    ⇒𝑛ethanol =1,2846 ≈0 , 0278 mol
2. Xác định chất hết - chất dư:
Theo phương trình, tỉ lệ mol là 1:1. Ta thấy  0 , 02 <0 , 0278, do đó butyric acid hết, ethanol dư. Tính toán lượng ester theo butyric acid.
⇒𝑛ester(lýthuyt) =𝑛butyricacid =0 , 02 mol
3. Tính khối lượng ester thực tế ( m𝑚):
  • Phân tử khối ethyl butyrate ( 𝐶6𝐻12 𝑂2):  𝑀 =116 g/mol
  • Hiệu suất phản ứng ( H𝐻) = 81%
    m=nester (lý thuyt)×Mester×H100𝑚=𝑛ester(lýthuyt)×𝑀ester×𝐻100
27 tháng 4
a. Viết phương trình phản ứng Phản ứng điều chế ethyl butyrate (ethyl butanoate) từ butyric acid (butanoic acid) và ethanol là phản ứng ester hóa, có axit  H2SO4𝐻2𝑆𝑂4 đặc làm xúc tác và đun nóng:
C3H7COOH+C2H5OHH2SO4đcC3H7COOC2H5+H2O𝐶3𝐻7𝐶𝑂𝑂𝐻+𝐶2𝐻5𝑂𝐻𝐻2𝑆𝑂4đc𝑡∘𝐶3𝐻7𝐶𝑂𝑂𝐶2𝐻5+𝐻2𝑂(Butyric acid + Ethanol   Ethyl butyrate + Nước)
b. Tính giá trị của m 1. Tính số mol các chất tham gia:
  • Phân tử khối của butyric acid ( C3H7COOH𝐶3𝐻7𝐶𝑂𝑂𝐻):  𝑀 =88 g/mol.
    nbutyric acid=1,7688=0,02mol𝑛butyricacid=1,7688=0,02mol
  • Phân tử khối của ethanol ( C2H5OH𝐶2𝐻5𝑂𝐻):  𝑀 =46 g/mol.
    nethanol=1,2846≈0,0278mol𝑛ethanol=1,2846≈0,0278mol
2. Xác định chất hết - chất dư:
Theo phương trình, tỉ lệ mol là  1 1. Ta thấy  0 , 02 <0 , 0278, do đó ethanol dư và tính toán lượng ester theo butyric acid (chất thiếu).
3. Tính khối lượng ester (m) theo lý thuyết:
  • Theo phương trình:  𝑛esterlýthuyt =𝑛butyricacid =0 , 02 mol.
  • Phân tử khối của ethyl butyrate ( C3H7COOC2H5𝐶3𝐻7𝐶𝑂𝑂𝐶2𝐻5):  𝑀 =116 g/mol.
    mlý thuyt=0,02×116=2,32gam𝑚lýthuyt=0,02×116=2,32gam
4. Tính khối lượng ester thực tế thu được (với hiệu suất 81%):
m=mlý thuyt×H100=2,32×81100=1,8792gam𝑚=𝑚lýthuyt×𝐻100=2,32×81100=1,8792gam
Đáp số:
  • a. Phương trình:  C3H7COOH+C2H5OH⇌C3H7COOC2H5+H2O𝐶3𝐻7𝐶𝑂𝑂𝐻+𝐶2𝐻5𝑂𝐻⇌𝐶3𝐻7𝐶𝑂𝑂𝐶2𝐻5+𝐻2𝑂
  • b.  𝑚 =1 , 8792 gam.

a) CH3CH2CH2COOH + C2H5OH ⇌ CH3CH2CH2COOC2H5 + H2O (H2SO4 đặc, t°) b) n(axit) = 1,76 / 88 = 0,02 mol n(ancol) = 1,28 / 46 ≈ 0,0278 mol → axit hết (chất giới hạn) n(este) lt = 0,02 mol m(este) lt = 0,02 × 116 = 2,32 g m(thực tế) = 2,32 × 81% = 1,8792 g ≈ 1,88 g

27 tháng 4

a,C3H7COOH+C2H5OH---------C3H7COOC2H5+H2

b,m=mlythuyet×H÷100=2,32×81÷100=1,8792gam

27 tháng 4
a. Viết phương trình phản ứng Phản ứng ester hóa giữa butyric acid và ethanol với xúc tác  H2SO4𝐻2𝑆𝑂4 đặc, đun nóng: C3H7COOH+C2H5OHC3H7COOC2H5+H2O𝐶3𝐻7𝐶𝑂𝑂𝐻+𝐶2𝐻5𝑂𝐻𝐻2𝑆𝑂4đc,𝑡𝑜𝐶3𝐻7𝐶𝑂𝑂𝐶2𝐻5+𝐻2𝑂 b. Tính giá trị của  m𝑚 1. Tính số mol các chất tham gia:
  • 𝑀𝐶3𝐻7𝐶𝑂𝑂𝐻 =88 g/mol ⇒𝑛acid =1,7688 =0 , 02 mol
  • 𝑀𝐶2𝐻5𝑂𝐻 =46 g/mol ⇒𝑛alcohol =1,2846 ≈0 , 0278 mol
2. Xác định chất giới hạn:
So sánh tỉ lệ mol:  0 , 02 <0 , 0278. Do đó, hiệu suất phản ứng tính theo butyric acid.
3. Tính khối lượng ester ( m𝑚):
  • Theo phương trình:  𝑛esterlýthuyt =𝑛acid =0 , 02 mol
  • Khối lượng ester theo lý thuyết:  0 , 02 ×116 =2 , 32 gam (với  𝑀ethylbutyrate =116)
  • Khối lượng ester thực tế với hiệu suất  81 %:
    m=2,32×81100=1,8792gam𝑚=2,32×81100=1,8792gam
Kết luận: Giá trị của  m𝑚 là 1,8792 gam.
28 tháng 4
𝐶𝐻3[𝐶𝐻2]2𝐶𝑂𝑂𝐻+𝐶2𝐻5𝑂𝐻𝐻2𝑆𝑂4đc,𝑡∘𝐶𝐻3[𝐶𝐻2]2𝐶𝑂𝑂𝐶2𝐻5+𝐻2𝑂 nacid=1,7688=0,02mol nalcohol=1,2846≈0,0278mol
  • Phân tử khối của ethyl butyrate ( C3H7COOC2H5𝐶3𝐻7𝐶𝑂𝑂𝐶2𝐻5):  𝑀ester =116 g/mol
  • Hiệu suất phản ứng ( H𝐻) =  81 %
    m=nester×Mester×H100=0,02×116×81100=1,8792gam𝑚=𝑛ester×𝑀ester×𝐻100=0,02×116×81100=1,8
30 tháng 4

Nxnxnx

Giá trị của m1,8792 gam.


30 tháng 4

543216789

1 tháng 5
a. Viết phương trình phản ứng Phản ứng giữa butyric acid (\(C_{3}H_{7}COOH\)) và ethanol (\(C_{2}H_{5}OH\)) với xúc tác \(H_{2}SO_{4}\) đặc, đun nóng: \(C_{3}H_{7}COOH+C_{2}H_{5}OH\xrightleftharpoons{H_{2}SO_{4},t^{o}}C_{3}H_{7}COOC_{2}H_{5}+H_{2}O\) b. Tính giá trị của m Để tính khối lượng ester (\(m\)), ta thực hiện các bước sau: 1. Tính số mol các chất tham gia:
  • \(n_{acid} = \frac{1,76}{88} = 0,02 \text{ mol}\)
  • \(n_{alcohol} = \frac{1,28}{46} \approx 0,0278 \text{ mol}\)
2. Xác định chất phản ứng hết (theo lý thuyết):
So sánh tỉ lệ mol: \(0,02 < 0,0278\). Do đó, acid phản ứng hết, ta tính lượng ester theo acid.
3. Tính khối lượng ester theo hiệu suất 81%:
  • Số mol ester thu được thực tế: \(n_{ester} = n_{acid} \times 81\% = 0,02 \times 0,81 = 0,0162 \text{ mol}\)
  • Khối lượng ester (\(m\)):
    \(m=0,0162\times 116=1,8792\text{\ gam}\)

Dưới đây là lời giải chi tiết cho bài toán điều chế **Ethyl butyrate** (ester có mùi dứa): ### a. Viết phương trình phản ứng Phản ứng giữa butyric acid và ethanol là phản ứng ester hóa, có xúc tác axit mạnh và đun nóng: * **Tên gọi:** Butyric acid + Ethanol \rightarrow Ethyl butyrate + Nước. ### b. Tính giá trị của m **Bước 1: Tính số mol các chất tham gia** * **Butyric acid (C_3H_7COOH):** M = 88 \text{ g/mol} * **Ethanol (C_2H_5OH):** M = 46 \text{ g/mol} **Bước 2: Xác định chất phản ứng hết** Theo phương trình, tỉ lệ mol là 1:1. So sánh số mol: 0,02 < 0,0278. Do đó, **Butyric acid** sẽ phản ứng hết trước, mọi tính toán về sản phẩm sẽ dựa trên số mol của acid. **Bước 3: Tính khối lượng ester theo lý thuyết** * **Ethyl butyrate (C_6H_{12}O_2):** M = 116 \text{ g/mol} * Theo lý thuyết: n_{ester} = n_{acid} = 0,02 \text{ mol} * Khối lượng lý thuyết (m_{LT}): **Bước 4: Tính khối lượng thực tế (m) với hiệu suất 81\%** **Kết quả:** Giá trị của m là **1,8792 gam**. **Lưu ý:** Ethyl butyrate là một trong những ester rất phổ biến trong công nghiệp thực phẩm để tạo hương liệu dứa nhân tạo. Nếu bạn cần tính toán thêm về nồng độ sau phản ứng, đừng ngần ngại hỏi nhé!

2 tháng 5

nxnnxjxj

2 tháng 5

Gxcuihcho

4 tháng 5
a. Phương trình phản ứng Phản ứng giữa butyric acid (\(C_{3}H_{7}COOH\)) và ethanol (\(C_{2}H_{5}OH\)) với xúc tác \(H_{2}SO_{4}\) đặc, đun nóng: \(C_{3}H_{7}COOH+C_{2}H_{5}OH\xrightleftharpoons{H_{2}SO_{4},t^{o}}C_{3}H_{7}COOC_{2}H_{5}+H_{2}O\) b. Tính giá trị của m Để tính khối lượng ester thu được, chúng ta thực hiện các bước sau: 1. Tính số mol các chất tham gia:
  • \(n_{butyric\ acid} = \frac{1,76}{88} = 0,02 \text{ mol}\)
  • \(n_{ethanol} = \frac{1,28}{46} \approx 0,0278 \text{ mol}\)
2. Xác định chất hết - chất dư (theo lý thuyết):
Dựa vào phương trình, tỉ lệ mol là 1:1. Ta thấy \(0,02 < 0,0278\), do đó hiệu suất phản ứng sẽ được tính theo số mol của butyric acid.
3. Tính khối lượng ester (\(m\)):
  • Theo phương trình, \(n_{ester\ (lý\ thuyết)} = n_{butyric\ acid} = 0,02 \text{ mol}\).
  • Khối lượng mol của ethyl butyrate (\(C_{3}H_{7}COOC_{2}H_{5}\)): \(M = 116 \text{ g/mol}\).
  • Khối lượng ester thực tế thu được với hiệu suất \(H = 81\%\):
    \(m=0,02\times 116\times \frac{81}{100}=1,8792\text{\ gam}\)
Kết luận: Giá trị của \(m\) là 1,8792 gam.

1,8792 gam.

11 tháng 5

Giá trị của m là 2,275 gam

11 tháng 5

1,8792 g

1,8792 g

12 tháng 5

1,8792

a). C3H7COOH + C2H5OH \(\overset{H2SO4,to}{\rightleftharpoons}\) C3H7COOC2H5 + H2O

b). nC3H7COOH = 0,02

nC2H5OH = 0,0278

\(\rarr\) nC3H7COOC2H5 =0,0162

mC3H7COOC2H5= 1,8792

IV. Fill in each blank in the passage with the correct word from the box. There are some extra words.independent, encourage, accidents, haircut,routines, try, injuries, independently,Tips on Teaching Teens How to Take Care of Their BodyIn order for your teens to be happy while they live (16) _________________, they will need to be successful at keeping their bodies healthy and clean. These life skills are taught throughout your teens' childhood and adolescence by encouraging good hygiene (17)...
Đọc tiếp
IV. Fill in each blank in the passage with the correct word from the box. There are some extra words.
independent, encourage, accidents, haircut,
routines, try, injuries, independently,
Tips on Teaching Teens How to Take Care of Their Body
In order for your teens to be happy while they live (16) _________________, they will need to be successful at keeping their bodies healthy and clean. These life skills are taught throughout your teens' childhood and adolescence by encouraging good hygiene (17) ________________ and healthy habits. Re-enforcing or establishing these good habits will help your teens keep them healthy and happy as they continue to grow up and become young adults.
The good hygiene habits that your teens should have are to brush their teeth twice daily, shower or bathe once daily, wash hair regularly, wash hands often, brush hair at least daily and get (18) _______________ regularly, trim nails once a week, take care of any (19) ________________ as they happen and until they are healed, and wear clean clothes.
It is okay to let good hygiene and healthy habits slide in small intervals, but (20) ________________ your teens to stick to the routine as much as possible. If you allow it to slide too long they can develop a bad habit and loose the good habits you have taught them.
1
21 tháng 10 2021

16. independently

17. routines

18. haircut

19. injuries

20. encourage

1. adequate /ˈædɪkwət/ (a) :  thỏa đáng, phù hợp

2. e-learning /ˈiː lɜːnɪŋ/(n) :  hình thức học trực tuyến

3. employable /ɪmˈplɔɪəbl/ (a) :  có thể được thuê làm việc

4. facilitate /fəˈsɪlɪteɪt/ (v) :  tạo điều kiện thuận lợi

Choose the best answer in each sentence below by circling it. 1. You are late. If you …… a few minutes earlier, you …… him.       A. came / would meet        B. had come / would have met          C. come / will meet            D. had come / would meet2. “Can I borrow your car for this evening?”“Sure, but Nora’s using it right now. If she …… it back in time, you’re welcome to borrow it.”     A. brings                B....
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Choose the best answer in each sentence below by circling it.

1. You are late. If you …… a few minutes earlier, you …… him. 

     A. came / would meet        B. had come / would have met    

     C. come / will meet            D. had come / would meet

2. “Can I borrow your car for this evening?”

“Sure, but Nora’s using it right now. If she …… it back in time, you’re welcome to borrow it.”

     A. brings                B. would bring                 C. will bring                       D. brought

3. We’re going to lose this game …… the team doesn’t start playing better soon.

A. if                             B. unless                      C. although                 D. whereas

4. If I …… somebody else, I’d like to be a film star.  

     A. could be                             B. would be           C. become       D. must be

5. If he had told me the truth, I …… him.     

     A. would have not punished                      B. would not have punished

     C. would not punish                                  D. will not punish

6. If they had not given me advice, I …… again.   

     A. would have failed                     B. would fail         C. would have been failed                        D. wouldn’t fail

7. …… immediately, I will call a policeman.

     A. Unless you leave           B. If you leave             C. If you didn’t leave                        D. Unless you left      

8. Bill …… more photographs if he …… more film.  

     A. would have taken / had had                  B. would have taken / had

     C. would take / has had                             D. would take / had had        

9. If there …… no floods last year, the crop …… better. 

     A. had been / would have been     B. were / would be  

     C. had / would have been               D. was / would have been

10. Had you told me that this was going to happen, I …… it.   

     A. would never have believed         B. don’t believe

    C. hadn’t believed                            D. can’t believe

11. If someone …… into the store, smile and say, “May I help you?”

     A. comes                B. came                       C. come                       D. could come

12. If I had a chance to do creative work, I …… happy working in an office.

     A. would be                       B. will be                     C. would have             D. will feel

13. If they …… soon, I’m not going to wait.  

     A. don’t come        B. won’t come                   C. hadn’t come        D. didn’t come

14. If I …… hungry, I …… something. But I am not hungry now.  

     A were / would eat                         B. had been / would have eaten        

     C. had been / would eat      D. were / would have eaten

15. You won’t pass the examination …… you study more.    

     A. unless         B. as           C. if                 D. whether

16. I’m playing tennis tomorrow …… it’s raining.    

     A. unless              B. if                   C. as long as    D. provided

17. Tell him to ring me if you …… him.   

     A. see                     B. saw             C. have seen                D. had seen

18. Unless she ……, she’ll be late.    

     A. hurries               B. didn’t hurry                        C. hurried                    D. doesn’t hurry

19. Would George be angry if I …… his bicycle without asking?  

     A. took      B. take             C. had taken    D. would take

20. I …… you a postcard while I was on holiday if I …… your address.

A. would have sent / had had       B. would have sent / had      

C. would send / had                      D. would send / had had

21.  …… still my friend if I were put in prison?  

     A. Would you be            B. Will you be           C. Would you        D. Would you are

22.  If anybody …… any question, please ask me after class.  

     A. has         B. have                C. don’t have                      D. doesn’t have

23.  If I weren’t working for an accounting firm, I …… in a bank.

A. would be working        B. will work         C. have worked         D. work

24. He said, “…… watch TV all the evening if you wish.”  

     A. You may           B. You have to              C. You need to             D. You should

25. If he ……, please tell me.    

     A. comes                B. won’t come                        C. will come                D. come

2
14 tháng 8 2021

Theo em nghĩ thì là C vì You thì ko thể dùng had đc.

14 tháng 8 2021

sao nhiều thế. Ai mà trả lời nổi

19 tháng 8 2025

1. Currently I’m renting a flat on Phao Dai Lang Street. It’s not so far from my workplace, only about 2 kilometers.

2. I think most Vietnamese people want to stay at home to relax and recover from their busy schedules at work and school. I also notice that some families in the city often go on a picnic during these days.

3. Well, I’m currently living in an apartment in a condo near the heart of Hanoi, so as you can imagine, there is no space for a garden there. However, I do have a lovely garden in my parents’ house where I grow all kinds of flowers and plants.

4.  Not really. I don’t think what I’m learning is practical and there is always a lot of homework and deadlines. But my friends at school are really nice. They are the main reason that I go to class.

5. Yes, I am. But I used to be a very hot-tempered kid who always got annoyed if someone kept me waiting even for 10 minutes.

6 tháng 1 2022

ko cần phải giao làm j , bọn tôi tự luyện .

31. She said if she were me, she wouldn’t buy that coat.

Sorry mình chỉ làm đc câu 31 thôi

Read the passage below and choose the best answer (A, B, C or D) to each question.The nuclear family, consisting of a mother, father, and their children f may be more an American ideal than an American reality. Of course, the so-called traditional American family was always more varied than we had been led to believe, reflecting the very different racial, ethnic, class, and religious customs among different American groups.The most recent government statistics reveal that only about one third...
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Read the passage below and choose the best answer (A, B, C or D) to each question.

The nuclear family, consisting of a mother, father, and their children f may be more an American ideal than an American reality. Of course, the so-called traditional American family was always more varied than we had been led to believe, reflecting the very different racial, ethnic, class, and religious customs among different American groups.

The most recent government statistics reveal that only about one third of all current American families fit the traditional mold and another third consists of married couples who either have no children or have none still living at home. Of the final one third, about 20 percent of the total number of American households are single people, usually women over sixty-five years of age. A small percentage, about 3 percent of the total, consists of unmarried people who choose to live together; and the rest, about 7 percent, are single, usually divorced parents, with at least one child.

1.   With what topic is the passage mainly concerned?

A. The traditional American family.

B.  The nuclear family.

C.  The ideal family.

D. The current American family

2.   The author implies that...................

A. there has always been a wide variety of family arrangements in the United States

B. racial, ethnic, and religious groups have preserved the traditional family structure

C. the ideal American family is the best structure  

D. fewer married couples are having children

3.  Who generally constitutes a one-person household?

A. A single in his twenties.

B. A single woman in her late sixties.

C. An elderly man.

D. A divorced woman,

4.  According to the passage, married couples whose children have grown or who have no children represent...................

A. 7 percent of households

B. 20 percent of households

C. 33, 3 percent of households

D. 3 percent of households

5.  The word "current" in line 7 is closest in meaning to...................

A. present                                     B. contemporary

C. now                                          D. modern

4
2 tháng 10 2021

1.A

2.D

3.B

4.D

5.A

2 tháng 10 2021

Hello

8 tháng 12 2023

Question 1. Member nations/ have / reason / attend / summits / discuss /shared goals.

Member nations have a reason to attend summits to discuss shared goals

Question 2. His respiratory health /gradually / become / better / since / he quit / smoke.

His respiratory health has gradually become better since he quitted smoking

Question 3. It / forbidden / litter / public places / Vietnam / keep the environment / clean. 

It is forbidden to litter in public places in Vietnam to keep the environment clean

Question 4. During / holiday season, / the city /  look / festive / joyful, / decorate / with / lights and decorations.

During the holiday season, the city looks festive and joyful, decorated with lights and decorations

Question 5. My mom / charge / resolve / family argument / find / solution.

My mom takes charge to resolve family arguments and find solutions

3 tháng 1 2024

1.Member nations have a reason for attending summits to discuss shared goals.

2.His respiratory health has gradually become better since he quit smoking.

3. It is forbidden to litter in public places in Vietnam to keep the environment clean.

 4.During the holiday season, the city looks festive and joyful, decorated with  lights and decorations.

 5.My mom was in charge of resolving the family argument and finding a solution.

 

ead the following passage then choose the word A,B,C or D that best fits each of the blank spaces.   More and more young people are ... (35) ... voluntary work abroad. The wild variety of jobs and destinations available is making it an increasingly attractive option for those who have just left school and have a year free before university. Many choose to spend these twelve months working in poor countries. There they will earn little ... (36) ... no money. But they will be doing something...
Đọc tiếp

ead the following passage then choose the word A,B,C or D that best fits each of the blank spaces.

   More and more young people are ... (35) ... voluntary work abroad. The wild variety of jobs and destinations available is making it an increasingly attractive option for those who have just left school and have a year free before university. Many choose to spend these twelve months working in poor countries. There they will earn little ... (36) ... no money. But they will be doing something useful - and enjoying the experience.

   The work may ... (37) ... of helping the local communities, for example by helping to build new road or provide water supplies to isolated rural villages. Other projects may concentrate more on conservation or environmental protection. ... (38) ... kind of job it is, it is certain to be ... (39) ... and worthwhile, and an experience that will never be forgotten.

35. A. doing       B. making       C. taking       D. getting

36. A. with       B. but       C. or       D. and

37. A. consist       B. include       C. contain       D. involve

38. A. Any       B. What       C. However       D. Whatever

39. A. challenging       B. dangerous       C. difficult       D. attracted

5
29 tháng 12 2021

35.B

36.C

37.B

38.D

39.A

Mình hơi ngu Anh nên nếu sai đừng chửi nhé

29 tháng 12 2021

35. A     36.C     37. A     38. D     39. A

7 tháng 12 2023

1 A balanced lifestyle can lead to improved health if it is adopted consistently.

2 Harry apologized to his mom for not having returned home on time.

3 It is obligatory for us to attend the mandatory training session.

4 It has been two months since he last experienced a family quarrel.

5 Susan's failure to understand the math problems made her feel frustrated.

8 tháng 12 2023

Question 1. A balanced lifestyle can lead to improved health if we adopt it consistently. (adopted)

=> A balanced lifestyle can lead to improved health if it is adopted consistently

Question 2. “I’m sorry for not returning home on time, Mom”, Harry said. (apologized)

Harry apologized to his mom for not returning home on time

Question 3. We are obligated to attend the mandatory training session. (to)

It is obligatory for us to attend the mandatory training session

Question 4. He hasn’t experienced a family quarrel for two months. (last)

The last time he experienced a family quarrel was two months ago

Question 5.  Susan failed to understand the math problems. That made her feel frustrated. (failure)

Susan's failure to understand the math problems made her feel frustrated.